Phosphate Minerals · uncommon

Vivianite

Vivianite is a hydrated iron phosphate that is colorless when fresh but oxidizes to deep blue and green. It forms bladed, prismatic, or fibrous crystals and earthy masses, and is a favorite of collectors for its rich color.

Deep blue-green bladed vivianite crystals
Photo: Robert M. Lavinsky · Wikimedia Commons · CC BY-SA 3.0

Vivianite properties at a glance

TypePhosphate Minerals
Chemical formulaFe3(PO4)2·8H2O
Mohs hardness1.75
Crystal systemmonoclinic
Lustervitreous
StreakBluish white
CleavagePerfect
FractureFibrous
Specific gravity2.68
Transparencytranslucent
Common colorsBlue, Green, Colorless
Rarityuncommon

Geology & background

Vivianite forms as a secondary mineral in iron-rich, phosphate-bearing environments, including the oxidation zones of ore deposits, clay sediments, peat bogs, and even buried organic remains.

Vivianite was named in 1817 after the English mineralogist John Henry Vivian. It has long interested collectors and has been noted by archaeologists for forming on buried bone and metal.

How to identify Vivianite

  • Look for deep blue to green bladed or prismatic crystals with a perfect cleavage.
  • Extreme softness, easily scratched by a fingernail, helps distinguish vivianite.
  • Darkening of color on exposure to light supports identification.

Where Vivianite is found

Vivianite occurs in iron-rich phosphate environments worldwide, with notable crystal localities in Bolivia and additional finds in the United States, Cameroon, Brazil, Australia, and Ukraine.

How much is Vivianite worth?

Entry-level specimen$10
Typical collector specimen$60
Premium specimen$400+

Value depends on crystal size, color, transparency, locality, damage, and overall aesthetics.

Common uses

  • Collector specimens
  • Historic blue pigment
  • Educational mineralogy
  • Mineralogical research

Interesting facts

  • Fresh vivianite is nearly colorless but darkens to deep blue or green as it oxidizes in light and air.
  • Vivianite has been found encrusting fossil bones, shells, and even archaeological artifacts.
  • It has historically been used as a blue pigment sometimes called blue iron earth.
  • Vivianite is extremely soft, easily marked by a fingernail.

Care & safety

Vivianite is extremely soft and brittle with perfect cleavage, so crystals damage very easily.

Avoid inhaling dust. Do not cut, grind, or polish unknown specimens without eye protection and a proper respirator.

Light sensitive and fragile. Vivianite is very soft and darkens in light; store it shielded from bright light and handle it minimally.

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