Sulfide Minerals · uncommon

Orpiment

Orpiment is a soft arsenic sulfide mineral famous for its brilliant lemon to golden-yellow color and resinous luster. It forms in low-temperature veins and hot spring deposits, commonly alongside red-orange realgar.

Bright lemon-yellow orpiment specimen
Photo: Christian Rewitzer · Wikimedia Commons · CC BY-SA 3.0

Orpiment properties at a glance

TypeSulfide Minerals
Chemical formulaAs2S3
Mohs hardness1.75
Crystal systemmonoclinic
Lusterresinous
StreakPale lemon yellow
CleavagePerfect on {010}
FractureUneven
Specific gravity3.49
Transparencytranslucent
Common colorsLemon yellow, Golden yellow, Orange-yellow, Brownish yellow
Rarityuncommon

Geology & background

Orpiment is an arsenic sulfide that forms in low-temperature hydrothermal veins, hot spring deposits, and volcanic fumaroles, often together with the related arsenic mineral realgar.

Orpiment was used as a yellow pigment in art and manuscripts for thousands of years and was also valued in early medicine and alchemy before its toxicity was fully understood.

How to identify Orpiment

  • Look for a soft, bright lemon to golden-yellow mineral with a resinous to pearly luster.
  • Orpiment is very soft at about 1.5 to 2 and has one perfect cleavage that yields flexible flakes.
  • Its pale yellow streak and association with red-orange realgar are strong identifying clues.

Where Orpiment is found

Orpiment occurs in low-temperature veins, hot springs, and fumaroles worldwide, with notable specimen localities in the United States, Peru, Russia, China, Romania, and Greece.

How much is Orpiment worth?

Entry-level specimen$10
Typical collector specimen$60
Premium specimen$400+

Value depends on color intensity, crystal development, luster, locality, size, and stability of the specimen.

Common uses

  • Historical yellow pigment
  • Collector specimens
  • Mineralogical study
  • Historical use in tanning and arts

Interesting facts

  • Orpiment was once an important yellow pigment known as King's yellow, despite being highly toxic.
  • Its name comes from the Latin auripigmentum, meaning gold pigment, for its rich yellow color.
  • Orpiment and realgar are closely associated arsenic sulfides that often occur together.
  • Realgar can slowly transform toward orpiment-like material after long exposure to light.

Care & safety

Orpiment is very soft and brittle and can flake apart or slowly degrade with light exposure.

Contains arsenic. Orpiment is an arsenic sulfide and is toxic; wash hands after handling and never ingest or inhale dust.

Avoid inhaling dust. Do not cut, grind, or polish unknown specimens without eye protection and a proper respirator.

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