Sulfide Minerals · uncommon

Realgar

Realgar is an arsenic sulfide mineral famous for its brilliant orange-red to red color and resinous luster. It forms soft, often translucent crystals and granular crusts, and slowly breaks down to a powder when exposed to light.

Bright orange-red realgar crystal specimen from Nevada
Photo: Robert M. Lavinsky · Wikimedia Commons · CC BY-SA 3.0

Realgar properties at a glance

TypeSulfide Minerals
Chemical formulaAs4S4
Mohs hardness1.75
Crystal systemmonoclinic
Lusterresinous
StreakOrange-red to yellow-orange
CleavageGood
FractureConchoidal
Specific gravity3.56
Transparencytranslucent
Common colorsRed, Orange-red, Orange
Rarityuncommon

Geology & background

Realgar forms in low-temperature hydrothermal veins, around hot springs and volcanic vents, and as a deposit associated with other arsenic and antimony minerals.

Realgar was used for centuries as a red-orange pigment in painting and as a source of arsenic for pyrotechnics, pest control, and early medicine, despite its serious toxicity.

How to identify Realgar

  • Look for a brilliant orange-red to red color, resinous luster, and an orange-red streak.
  • Realgar is very soft and translucent, and old specimens may show a dusty yellow alteration crust.
  • It commonly occurs with yellow orpiment in low-temperature veins, which helps confirm identification.

Where Realgar is found

Realgar occurs in low-temperature hydrothermal veins and hot-spring deposits worldwide, with notable specimen localities in China, Romania, the United States, Peru, Switzerland, and Germany.

How much is Realgar worth?

Entry-level specimen$10
Typical collector specimen$70
Premium specimen$450+

Value depends on color, crystal size and form, condition, locality, matrix, and degree of light damage.

Common uses

  • Historical red pigment
  • Arsenic source
  • Pyrotechnics
  • Collector specimens
  • Educational mineral examples

Interesting facts

  • Realgar slowly disintegrates into a yellow-orange powder when exposed to light over time.
  • Its name comes from an Arabic phrase meaning powder of the mine.
  • Realgar was used historically as a vivid red-orange pigment despite its toxicity.
  • It commonly occurs alongside the yellow arsenic sulfide orpiment, into which it can alter.

Care & safety

Realgar is very soft and fragile and slowly breaks down to powder when exposed to light.

Toxic arsenic mineral. Realgar contains arsenic; do not lick, ingest, or inhale dust, wash hands after handling, and never cut or grind it.

Store away from light. Light exposure degrades realgar into a fine powder, so keep specimens in dark, enclosed storage.

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