Oxide Minerals · common

Pyrolusite

Pyrolusite is the most common manganese oxide ore mineral, with a steel-gray to black color and metallic to dull luster. It typically occurs as massive, fibrous, or radiating aggregates and often forms branching dendrites on rock surfaces.

Botryoidal pyrolusite specimen with steel-gray metallic surface
Photo: Aram Dulyan · Wikimedia Commons · Public domain

Pyrolusite properties at a glance

TypeOxide Minerals
Chemical formulaMnO2
Mohs hardness6.25
Crystal systemtetragonal
Lustermetallic
StreakBlack to bluish black
CleavagePerfect prismatic
FractureUneven
Specific gravity5
Transparencyopaque
Common colorsBlack, Steel gray, Bluish gray
Raritycommon

Geology & background

Pyrolusite forms when manganese is oxidized near the surface, precipitating from groundwater in bogs, lake beds, and weathered deposits, often as massive, fibrous, or dendritic growths.

Pyrolusite has long been used to decolorize glass and to make manganese compounds, and it became essential to modern industry as the principal ore for manganese in steel alloys.

How to identify Pyrolusite

  • Look for a steel-gray to black metallic mineral that leaves a black streak and can soil the fingers.
  • Massive and fibrous habits are typical, and branching black dendrites are a recognizable form.
  • Soft, sooty manganese oxide coatings are commonly pyrolusite mixed with related manganese minerals.

Where Pyrolusite is found

Pyrolusite occurs in weathered and sedimentary manganese deposits worldwide, with notable specimen localities in Germany, India, Brazil, South Africa, the United States, and Ukraine.

How much is Pyrolusite worth?

Entry-level specimen$5
Typical collector specimen$35
Premium specimen$200+

Value depends on crystal development, habit, locality, associated minerals, and overall condition.

Common uses

  • Manganese ore for steel
  • Glassmaking and decolorizing
  • Dry-cell batteries
  • Pigments and chemicals
  • Collector specimens

Interesting facts

  • Pyrolusite is the most important ore of manganese, a key ingredient in steelmaking.
  • Branching, fern-like pyrolusite dendrites on rock are often mistaken for fossil plants.
  • Its name comes from Greek words for fire and to wash, since it was used to remove color from glass.
  • Well-formed pyrolusite crystals are uncommon, so most specimens are massive or fibrous.

Care & safety

Pyrolusite ranges from hard crystals to soft, crumbly masses that can flake and stain on handling.

Avoid inhaling dust. Do not cut, grind, or polish unknown specimens without eye protection and a proper respirator.

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